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PREPARATION OF AN AQUEOUS DISPERSION OF COPOLYMER PARTICLES OF VINYL ACETATE AND A CYCLIC KETENE ACETAL MONOMER

The present invention relates to a method comprising the steps of a) contacting under emulsion polymerization conditions vinyl acetate; a cyclic ketene acetal monomer; and a monoethylenically unsaturated acid monomer or a salt thereof; to form an aqueous dispersion of copolymer particles comprising structural units of vinyl acetate, the cyclic ketene acetal, and the monoethylenically unsaturated acid monomer or a salt thereof; wherein the cyclic ketene acetal monomer is characterized by following structure: where n and the R groups are as defined herein. The method of the present invention provides a water-borne dispersion that is substantially free of volatile organic solvents and that provides a readily degradable polymer that is useful, for example, in the manufacture of biodegradable packaging products.

Publication date: 10/10/2020

Number: CA3077845A1 (A1)

Applicant: ROHM & HAAS?[US]

Inventor: CARTER MATTHEW?[US]; EVEN RALPH C?[US] (1)

Espacenet (LATIPAT)



      

This project has received funding from the Bio Based Industries Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement No 837761.