Technological watch

Improvement of polyvinyl alcohol/casein blend film properties by adding cellulose nanocrystals

The aim of this study is to present a biopolymeric food packaging material as an alternative to synthetic polymers. Nanocrystals reinforcement and chemical crosslinking methods were used to improve the physicochemical properties of poly(vinyl alcohol)/casein films required for use as packaging material. As a result, the prepared films may be suitable for usage as ecologically friendly packaging materials with strong moisture barriers and mechanical capabilities as an alternative to synthetic ones.This study aims to prepare and examine the properties of poly(vinyl alcohol)/casein (PVA/CAS) based films reinforced with cellulose nanocrystals (NC), which can be presented as an alternative to petroleum?based polymer packaging materials. PVA/CAS and 0.5–1–3–5?wt% NC containing PVA/CAS biocomposite films were prepared by solution casting method. Afterward, the 1NC film, which exhibited the best mechanical properties, was crosslinked with various amounts of glyoxal. Structural, morphological (polarized optical microscope), mechanical (tensile), thermal (differential scanning calorimetry, thermogravimetric analysis), contact angle, and water vapor transmission rate (WVTR) properties of the samples were investigated. The 1NC film exhibited the highest tensile strength (TS) and elongation values in PVA/CAS/NC films, and its mechanical properties decreased due to agglomeration with increasing NC amount. As expected, crosslinking improved the TS. The thermal stability of the PVA/CAS film was generally improved with the addition of NC and crosslinking. The high WVTR value of the PVA/CAS film decreased with the addition of NC and the 1NC film presented the lowest value. Thanks to the complex structure formed as a result of crosslinking and the reduced free volume, the WVTR of the 1NC film has reduced. The results showed that PVA/CAS?based films with good mechanical properties and water vapor barrier are promising as packaging materials.

Publication date: 26/01/2023

Journal of Vinyl and Additive Technology


This project has received funding from the Bio Based Industries Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement No 837761.