Technological watch

New Method Uses UV Light to Make PLA More Biodegradable

Many plastics that are labelled as biodegradable are only compostable under industrial conditions, but scientists at the University of Bath have now found a way to make plastics break down using only UV light.
Limited Degradability
As a result of increasing public concern over plastic waste, PLA (Poly(lactic acid)), created using lactic acid from the fermentation of sugars, is now widely used as a renewable, sustainable alternative to plastics derived from crude oil products - used in everything from disposable cups and teabags to 3D printing and packaging.
It is often labelled as biodegradable, however it has limited degradability in natural environments, for example in soil or in seawater, and it only degrades under industrial composting conditions of high temperatures and humidity – not achievable in domestic compost heaps.
Making PLA Truly Biodegradable
Scientists at the Centre for Sustainable and Circular Technologies (CSCT) at the University of Bath have developed a way that could make these plastics more degradable in the natural environment.
The team found that they can tweak the degradability of the plastic by incorporating different amounts of sugar molecules into the polymer.
They found that incorporating as little as three per cent sugar polymer units into PLA led to 40% degradation within six hours of exposure to UV light.
Most promisingly, the technology is compatible with existing plastic manufacturing processes, meaning it could potentially be tested and adopted quickly by the plastics industry.
Dr Antoine Buchard, Royal Society University Research Fellow and Reader in Polymer Chemistry from the CSCT, led the research, which was supported by the Royal Society. Buchard said: “Lots of plastics are labelled as biodegradable, but unfortunately this is only true if you dispose of it in an industrial waste composter - if put into domestic compost heaps, it can last for years."
Most PLA plastics are made up of long polymer chains which can be difficult for water and enzymes to break down. Our research adds sugars into the polymer chains, linking everything together by bonds that can be broken using UV light. This weakens the plastic, breaking it down into smaller polymer chains that are then more sensitive to hydrolysis,” added Buchard.
Source: University of Bath

Publication date: 31/05/2022

Omnexus (news)


This project has received funding from the Bio Based Industries Joint Undertaking under the European Union’s Horizon 2020 research and innovation programme under grant agreement No 837761.